Pablo Espinet
cinquima.uva.es
0000-0001-8649-239X
301 papers found
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Ranking Ligands by Their Ability to Ease (C6F5)2NiIIL → Ni0L + (C6F5)2 Coupling versus Hydrolysis: Outstanding Activity of PEWO Ligands
Fluorinated vs Nonfluorinated PR2(biaryl) Ligands and Their [AuCl(L)] Complexes: Synthesis, X-ray Structures, and Computational Study of Weak Interactions. Bond, No Bond, and Beyond
Striking Increase in Hole Mobility upon Metal Coordination to Triphenylene Schiff Base Semiconducting Multicolumnar Mesophases
Experimental and DFT Study of the [AuAr(AsPh3)]-Catalyzed cis/trans Isomerization of [PdAr2(AsPh3)2] (Ar = C6F5 or C6Cl2F3): Alternative Mechanisms and Its Switch upon Pt for Pd Substitution
Reactivity of Fluorinated-Chalcone Phosphines, RPEWO-F4, Induced by C–F Activation upon Coordination to PdCl2
Fluorescent perylenylpyridine complexes: an experimental and theoretical study
Striking ligand-disproportionative Cl/aryl scrambling in a simple Au(III) system. Solvent role, driving forces and mechanisms.
Experimental Study of Speciation and Mechanistic Implications when Using Chelating Ligands in Aryl‒Alkynyl Stille Coupling
E–Z Isomerization of Phosphine-Olefin (PEWO-F4) Ligands Revealed upon PdCl2 Capture: Facts and Mechanism
RhI Ar/AuI Ar′ Transmetalation: A Case of Group Exchange Pivoting on the Formation of M−M′ Bonds through Oxidative Insertion
d8⋯d10 RhI⋯AuI interactions in Rh 2,6-xylylisocyanide complexes with [Au(CN)2]−: bond analysis and crystal effects
4-Pyridylisocyanide gold(i) and gold(i)-plus-silver(i) luminescent and mechanochromic materials: the silver role
Li+ and K+ ionic conductivity in ionic nematic liquid crystals based on 18-diaza-crown ether substituted with six decylalkoxy-p-cyanobiphenyl chains
Comparing Protonolysis and Transmetalation Reactions: Microcalorimetric Studies of C–AuI Bonds in [AuRL] Complexes
Coordinatively Unsaturated [RhCp*Rf2] (Cp* = C5Me5; Rf = C6F3Cl2-3,5), General Precursor to Cp*-Diaryl and Cp*-Halo-Aryl RhIII Complexes. Observing and Testing the Effect of Cp* as Electronic Buffer
Triphenylene-Imidazolium Salts and Their NHC Metal Complexes, Materials with Segregated Multicolumnar Mesophases
Hidden aryl-exchange processes in stable 16e Rh III [RhCp* Ar 2] complexes, and their unexpected transmetalation mechanism
Highly enantioselective addition of dimethylzinc to fluorinated alkyl ketones, and the mechanism behind it
Hidden aryl-exchange processes in stable 16e RhIII [RhCp*Ar2] complexes, and their unexpected transmetalation mechanism
Coordinatively Unsaturated [RhCp* Rf2](Cp*= C5Me5; Rf= C6F3Cl2-3, 5), General Precursor to Cp*-Diaryl and Cp*-Halo-Aryl RhIII Complexes. Observing and Testing the Effect of Cp* as Electronic Buffer
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