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Royal Society of Chemistry, Chemical Communications, 34(55), p. 5005-5008, 2019

DOI: 10.1039/c9cc01377f

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d8⋯d10 RhI⋯AuI interactions in Rh 2,6-xylylisocyanide complexes with [Au(CN)2]−: bond analysis and crystal effects

Journal article published in 2019 by Verónica Conejo-Rodríguez ORCID, Marconi N. Peñas-Defrutos ORCID, Pablo Espinet ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The well-known [RhL4]n(anion)n structures, with RhI⋯RhI d8⋯d8 interactions, are replaced by others with RhI⋯AuI d8⋯d10 interactions such as [{RhL4}{Au(CN)2}] (L = 2,6-xylylisocyanide) or [{RhL4}{Au(CN)2}{RhL4}{Au2(CN)3}·4(CHCl3)]∞ when the anion is [Au(CN)2]−.