Published in
Royal Society of Chemistry, Dalton Transactions, 32(49), p. 11336-11345, 2020
DOI: 10.1039/d0dt02335c
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Experimental Study of Speciation and Mechanistic Implications when Using Chelating Ligands in Aryl‒Alkynyl Stille Coupling
Journal article published in 2020 by
Ana Mª Maria Gallego Díaz 
,
Marconi N. Peñas-Defrutos ,
Guillermo Marcos-Ayuso ,
Jose M. Martin-Alvarez ,
Jose Miguel Martín Álvarez,
Jesus M. M. Martinez-Ilarduya ,
Pablo Espinet
,
Marconi N. Peñas-Defrutos ,
Guillermo Marcos-Ayuso ,
Jose M. Martin-Alvarez ,
Jose Miguel Martín Álvarez,
Jesus M. M. Martinez-Ilarduya ,
Pablo Espinet
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Abstract
The leaving group and the solvent are critical for transmetalation of alkynyl to Pd chelate complexes in a Stille process.