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Royal Society of Chemistry, Dalton Transactions, 28(48), p. 10412-10416, 2019

DOI: 10.1039/c9dt01618j

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4-Pyridylisocyanide gold(i) and gold(i)-plus-silver(i) luminescent and mechanochromic materials: the silver role

Journal article published in 2019 by Verónica Conejo-Rodríguez ORCID, Marconi N. Peñas-Defrutos ORCID, Pablo Espinet ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

X-Ray and DFT studies support that the red-shift of luminescence from [AuAr(CNPy-4)] (Ar = C6F5, C6F3Cl2-3,5) to [Ag[AuAr(CNPy-4)]2](BF4) is not due to non-existent Au⋯Ag interactions but to adoption of structures with shorter Au⋯Au distances.