Published in
Royal Society of Chemistry, Organic and Biomolecular Chemistry, 1(16), p. 70-76
DOI: 10.1039/c7ob02488f
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Thermally induced N–S bond insertion reaction of diazo compounds with N-sulfenylsuccinimides: synthesis of sulfides and mechanism studies
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Abstract
A metal-free gem-functionalization reaction of diazo compounds via a formal N–S bond insertion process under mild conditions is presented.