Published in
Royal Society of Chemistry, Dalton Transactions, 35(46), p. 11547-11551
DOI: 10.1039/c7dt02575k
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Preparation of monopodal and bipodal aluminum surface species by selective protonolysis of highly reactive [AlH3(NMe2Et)] on silica
Journal article published in 2017 by
D. W. Sauter,
V. Chiari,
N. Aykac,
S. Bouaouli,
L. Perrin 
,
L. Delevoye,
R. M. Gauvin ,
K. C. Szeto,
C. Boisson ,
M. Taoufik
,
L. Delevoye,
R. M. Gauvin ,
K. C. Szeto,
C. Boisson ,
M. Taoufik
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Abstract
The reaction of [AlH3(NMe2Et)] with silica treated at 200 °C leads to a well-defined bipodal aluminum hydride while with silica treated at 700 °C a mixture of mono- and bi-podal aluminum hydrides is obtained.