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Royal Society of Chemistry, Dalton Transactions, 31(46), p. 10440-10451

DOI: 10.1039/c7dt02243c

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Terminal vs. bridging coordination of CO and NO ligands after decarbonylation of [W2Cp2(μ-PR2)(CO)3(NO)] complexes (R = Ph, Cy). An experimental and computational study

Journal article published in 2017 by M. Angeles Alvarez, M. Esther García ORCID, Daniel García-Vivó ORCID, M. Teresa Rueda, Miguel A. Ruiz ORCID, Adrián Toyos, M. Fernanda Vega
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Photolysis of the title complexes yields κ1:η2-CO-bridged derivatives, and not their unsaturated κ1:κ1-NO-bridged isomers, despite their similar thermodynamic stability.