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Royal Society of Chemistry, Organic and Biomolecular Chemistry, 29(15), p. 6167-6176

DOI: 10.1039/c7ob01312d

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C–ON bond homolysis of alkoxyamines: when too high polarity is detrimental

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

In this article, previous multi-parameter linear relationships are amended using a parabolic model to describe the effect of EWGs in the alkyl fragment of alkoxyamines on the homolysis rate constant kd.