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Royal Society of Chemistry, Dalton Transactions, 3(46), p. 947-955

DOI: 10.1039/c6dt03733j

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Ln polyoxocations: yttrium oxide solution speciation & solution deposited thin films

Journal article published in 2017 by David A. Marsh, Sara Goberna-Ferrón ORCID, Mary K. Baumeister, Lev N. Zakharov, May Nyman, Darren W. Johnson ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The lanthanide hexamer (Ln6) is a reactive hydrolysis product of simple lanthanide nitrates.Ln6dissolved in coordinating solvents converts toLn16, a hydrolysis product intermediate betweenLn6and Ln2O3. X-ray scattering of solutions reveals Ln3+-radius-dependent reaction pathways.