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Royal Society of Chemistry, Dalton Transactions, 11(46), p. 3510-3525, 2017

DOI: 10.1039/c7dt00132k

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Chemistry of CS2- and SCNPh-adducts of the pyramidal phosphinidene-bridged complex [Mo2Cp(μ–κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)(PMe3)]

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Heterocumulene insertion into the metallocene Mo–P bond of the title complex enables further addition of different electrophiles at the P, S or N sites.