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Royal Society of Chemistry, Chemical Communications, 1(48), p. 124-126, 2012

DOI: 10.1039/c1cc14744g

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Melting point suppression in new lanthanoid(iii) ionic liquids by trapping of kinetic polymorphs: an in situsynchrotron powder diffraction study

Journal article published in 2012 by Anthony S. R. Chesman, Mei Yang, Bert Mallick, Tamsyn M. Ross, Ian A. Gass, Glen B. Deacon ORCID, Stuart R. Batten, Anja-Verena Mudring ORCID
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This paper is available in a repository.

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Abstract

The complexes (N(4444))(3)[Ln(dcnm)(6)] (Ln = La-Nd, Sm; N(4444) = tetrabutylammonium) display a decrease in the melting point upon fast cooling from a melt, which is shown by in situ synchrotron based X-ray powder diffraction to be due to the formation of a second, less thermodynamically stable, polymorph.