Published in
Royal Society of Chemistry, Chemical Communications, 1(48), p. 124-126, 2012
DOI: 10.1039/c1cc14744g
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Melting point suppression in new lanthanoid(iii) ionic liquids by trapping of kinetic polymorphs: an in situsynchrotron powder diffraction study
Journal article published in 2012 by
Anthony S. R. Chesman,
Mei Yang,
Bert Mallick,
Tamsyn M. Ross,
Ian A. Gass,
Glen B. Deacon 
,
Stuart R. Batten,
Anja-Verena Mudring
,
Stuart R. Batten,
Anja-Verena Mudring
This paper is available in a repository.
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Abstract
The complexes (N(4444))(3)[Ln(dcnm)(6)] (Ln = La-Nd, Sm; N(4444) = tetrabutylammonium) display a decrease in the melting point upon fast cooling from a melt, which is shown by in situ synchrotron based X-ray powder diffraction to be due to the formation of a second, less thermodynamically stable, polymorph.