Published in
Royal Society of Chemistry, Organic and Biomolecular Chemistry, 3(15), p. 662-671
DOI: 10.1039/c6ob02486f
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Reaction of phosphinylated nitrosoalkenes with electron-rich heterocycles. Electrophilic aromatic substitution vs. cycloaddition
Journal article published in 2017 by
Jesús M. de los Santos,
Gloria Rubiales,
Zouhair Es Sbai,
Ana M. Ochoa de Retana 
,
Francisco Palacios
,
Francisco Palacios
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Abstract
An experimental and theoretical study describe the behavior of phosphinyl nitrosoalkenes with indole, pyrrole and 2,5-dimethylpyrrole. Both, an electrophilic aromatic substitution and a [4 + 2] cycloaddition mechanism, were evaluated.