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Royal Society of Chemistry, Physical Chemistry Chemical Physics, 24(18), p. 16555-16565

DOI: 10.1039/c6cp02608g

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Understanding M–ligand bonding and mer-/fac-isomerism in tris(8-hydroxyquinolinate) metallic complexes

Journal article published in 2016 by Carlos F. R. A. C. Lima ORCID, Ricardo J. S. Taveira, José C. S. Costa ORCID, Ana M. Fernandes, André Melo ORCID, Artur M. S. Silva ORCID, Luís M. N. B. F. Santos
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This paper is available in a repository.

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Abstract

mer-/fac-Isomerism in tris(8-hydroxyquinolinate) complexes is ruled by the interplay between steric and bonding factors. The M–ligand bond has strong covalent character and allows for through-ligand electron delocalization.