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Royal Society of Chemistry, Physical Chemistry Chemical Physics, 11(19), p. 7990-7995, 2017

DOI: 10.1039/c6cp07530d

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Surface heterogeneity and inhomogeneous broadening of vibrational line profiles

Journal article published in 2017 by Skandar Taj, Diane Baird, Victoria Frankland, Alexander Rosu-Finsen ORCID, Mark P. Collings, Martin R. S. McCoustra ORCID
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This paper is available in a repository.

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Abstract

The surface heterogeneity of amorphous silica (aSiO2) has been probed using coverage dependent temperature programmed desorption (TPD) of a simple probe molecule, carbon monoxide (CO), and is used to explain the inhomogeneous broadening of the CO stretching vibration in the infrared.