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Royal Society of Chemistry, Polymer Chemistry, 27(7), p. 4525-4530, 2016

DOI: 10.1039/c6py00818f

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Synthesis of poly(allyl 2-ylidene-acetate) and subsequent post-polymerization modification via thiol–ene reaction

Journal article published in 2016 by Tim Krappitz, Daniel Brauer, Patrick Theato ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Poly(allyl 2-ylidene-acetate) (Mw = 125 300 g mol−1) was synthesized via rhodium mediated catalysis of allyl 2-diazoacetate and its polymerization kinetics and polymer characteristics are presented and discussed. Furthermore, post-polymerization modification utilized the reactive character of poly(allyl 2-ylidene-acetate) by means of thiol–ene reactions.