Royal Society of Chemistry, Polymer Chemistry, 27(7), p. 4525-4530, 2016
DOI: 10.1039/c6py00818f
Full text: Unavailable
Poly(allyl 2-ylidene-acetate) (Mw = 125 300 g mol−1) was synthesized via rhodium mediated catalysis of allyl 2-diazoacetate and its polymerization kinetics and polymer characteristics are presented and discussed. Furthermore, post-polymerization modification utilized the reactive character of poly(allyl 2-ylidene-acetate) by means of thiol–ene reactions.