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Royal Society of Chemistry, CrystEngComm

DOI: 10.1039/c7ce01826f

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Co–Co and Co–Fe cyano-bridged pentanuclear clusters based on a methylpyrazinyl-diamine tetradentate ligand: spin crossover and metal substitution effects

Journal article published in 2017 by Bin Fei, Jian Zhou, Zheng Yan, Sergii I. Shylin ORCID, Vadim Ksenofontov, Il'ya A. Gural'skiy ORCID, Xin Bao ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A pentanuclear [CoII3CoIII2] cluster complex has been developed by a solvothermal synthesis. Its highly stable metal-mixed Fe–Co derivatives display robust spin crossover (T1/2 = 268 K) controlled by the degree of substitution.