Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 22(18), p. 15118-15132, 2016
DOI: 10.1039/c6cp01982j
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Pressure dependent low temperature kinetics for CN + CH3CN: competition between chemical reaction and van der Waals complex formation
Journal article published in 2016 by
Chantal Sleiman,
Sergio González,
Stephen J. Klippenstein 
,
Dahbia Talbi,
Gisèle El Dib,
André Canosa
,
Dahbia Talbi,
Gisèle El Dib,
André Canosa
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Abstract
The gas phase reaction between the CN radical and acetonitrile CH3CN was investigated experimentally with a CRESU apparatus and a slow flow reactor as well as theoretically to explore the temperature and pressure dependence of its rate coefficient from 354 K down to 23 K.