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Royal Society of Chemistry, Dalton Transactions, 32(45), p. 12691-12701

DOI: 10.1039/c6dt02565j

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Synthesis of a labile sulfur-centred ligand, [S(H)C(PPh2S)2]−: structural diversity in lithium(i), zinc(ii) and nickel(ii) complexes

Journal article published in 2016 by Ramalingam Thirumoorthi, Tristram Chivers, Susanna Häggman, Akseli Mansikkamäki ORCID, Ian S. Morgan, Heikki M. Tuononen, Manu Lahtinen, Jari Konu
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Abstract

Structural isomerism: formation of a labile tridentate sulfur-ligand led to the isolation of the first examples of Ohand SP Ni(ii) isomers of the same ligand in [Ni{S(H)C(PPh2S)2}2] and their fluxional behaviour is examined.