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Royal Society of Chemistry, Chemical Communications, 44(52), p. 7106-7109, 2016

DOI: 10.1039/c6cc02918c

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NiIItetrahydronorcorroles: antiaromatic porphyrinoids with saturated pyrrole units

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

While hydrogenated porphyrins are abundant in natural and synthetic compounds, antiaromatic hydrogenated porphyrinoids have not been synthesized to date. Here, we report bacteriochlorin-like NiII tetrahydronorcorrole complexes as the first examples of antiaromatic porphyrinoids that contain saturated pyrrole units.