Published in
Royal Society of Chemistry, Materials Chemistry Frontiers, 9(1), p. 1773-1785, 2017
DOI: 10.1039/c7qm00096k
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Time-evolved, far-red, circularly polarised luminescent polymer aggregates endowed with sacrificial helical Si–Si bond polymers
Journal article published in 2017 by
Michiya Fujiki 
,
Shosei Yoshimoto
,
Shosei Yoshimoto
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Abstract
Non-charged helical polysilanes (PSi) were spontaneously endowed with CPL on the order of gem = ±0.02 at 700 nm when non-helical red- and far-red π-conjugated polymeric (PF8DBT) aggregates were employed after ageing at 20–25 °C for 24 h, followed by PSi-selective photoscissoring at 313 nm for 60 s.