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Royal Society of Chemistry, Chemical Communications, 62(53), p. 8664-8666

DOI: 10.1039/c7cc04396a

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Synthesis of rare-earth-metal-in-cryptand dications, [Ln(2.2.2-cryptand)]2+, from Sm2+, Eu2+, and Yb2+ silyl metallocenes (C5H4SiMe3)2Ln(THF)2

Journal article published in 2017 by Daniel N. Huh ORCID, Christopher M. Kotyk ORCID, Milan Gembicky ORCID, Arnold L. Rheingold ORCID, Joseph W. Ziller ORCID, William J. Evans ORCID
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This paper is available in a repository.

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Abstract

Ln2+-in-cryptand complexes (Ln = Sm, Eu, Yb) containing +2 ions surrounded only by neutral ligands are readily formed from silyl metallocenes.