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Royal Society of Chemistry, Dalton Transactions, 9(46), p. 2803-2820, 2017

DOI: 10.1039/c6dt04661d

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Classical hydrogen bonding and stacking of chelate rings in new copper(ii) complexes

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Three new copper(ii) complexes, viz., [Cu(L)(NO3)(H2O)]H2O 1, [Cu(L)(H2O)2]NO32 and [Cu2(L)2(pyrazine)](ClO4)2·4H2O 3, were prepared using a biomimetic synthesis strategy [HL = 4-chloro-2-{(E)-[2-(pyridin-2-yl)hydrazinylidene]methyl}phenol]. In complex 3, stacking of chelates rings was observed.