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Royal Society of Chemistry, Physical Chemistry Chemical Physics, 27(18), p. 18424-18430, 2016

DOI: 10.1039/c6cp01004k

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Experimentally probing the libration of interfacial water: the rotational potential of water is stiffer at the air/water interface than in bulk liquid

Journal article published in 2016 by Yujin Tong ORCID, Tobias Kampfrath, R. Kramer Campen ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Vibrational sum frequency spectroscopy measurements reveal that the libration frequency of interfacial water is significantly higher than bulk liquid water, suggesting that water's rotational potential stiffens on moving from the bulk liquid to the air/water interface.