Royal Society of Chemistry, Physical Chemistry Chemical Physics, 34(19), p. 22700-22710, 2017
DOI: 10.1039/c7cp04601d
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The concept of efficient electrolysis by linking photoelectrochemical biphasic H2 evolution and water oxidation processes in the cathodic and anodic compartments of an H-cell, respectively, is introduced. The concepts viability is demonstrated by electrochemical H2 production from water splitting utilising a polarised water–organic interface in a prototype H-cell.