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Royal Society of Chemistry, Catalysis Science & Technology, 22(7), p. 5343-5353, 2017

DOI: 10.1039/c7cy00521k

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Heterocyclic bismuth(iii) compounds with transannular N→Bi interactions as catalysts for the oxidation of thiophenol to diphenyldisulfide

Journal article published in 2017 by Ana M. Toma, Ciprian I. Raţ ORCID, Octavian D. Pavel ORCID, Christopher Hardacre ORCID, Tobias Rüffer ORCID, Heinrich Lang, Michael Mehring ORCID, Anca Silvestru ORCID, Vasile I. Pârvulescu ORCID
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This paper is available in a repository.

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Abstract

Aerial oxidation of thiophenol to diphenyl disulfide proceeds with high reaction rates, total conversion and selectivity in ionic liquids by using diorganobismuth(iii) catalysts.