Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 6(19), p. 4352-4359, 2017
DOI: 10.1039/c6cp08308k
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Effect of substituents and anions on the phase behavior of Ru(ii) sandwich complexes: exploring the boundaries between ionic liquids and ionic plastic crystals
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Abstract
Salts of cationic ruthenium sandwich complexes bearing ethyl or longer substituents are ionic liquids, whereas salts with shorter substituents showed ionic plastic crystal phases.