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Royal Society of Chemistry, Catalysis Science & Technology, 14(7), p. 3128-3142, 2017

DOI: 10.1039/c7cy00875a

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Reactivity of cationic α-diimine cyclopentadienyl nickel complexes towards AlEt2Cl: synthesis, characterisation and ethylene polymerisation

Journal article published in 2017 by Clara S. B. Gomes, Alejandro F. G. Ribeiro, Anabela C. Fernandes, Artur Bento, M. Rosário Ribeiro ORCID, Gabriele Kociok-Köhn, Sofia I. Pascu, M. Teresa Duarte ORCID, Pedro T. Gomes ORCID
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This paper is available in a repository.

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Abstract

Cationic α-diimine cyclopentadienyl nickel complexes transform into intermediates upon reaction with AlEt2Cl giving rise to active ethylene polymerisation catalysts.