Published in
Royal Society of Chemistry, Catalysis Science & Technology, 8(7), p. 1654-1661, 2017
DOI: 10.1039/c7cy00342k
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Efficient acceptorless dehydrogenation of secondary alcohols to ketones mediated by a PNN-Ru(II) catalyst
Journal article published in 2017 by
Zheng Wang 
,
Bing Pan,
Qingbin Liu,
Erlin Yue,
Gregory A. Solan ,
Yanping Ma,
Wen-Hua Sun
,
Bing Pan,
Qingbin Liu,
Erlin Yue,
Gregory A. Solan ,
Yanping Ma,
Wen-Hua Sun
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Abstract
The ruthenium(ii) complex, [fac-PNHN]RuCl2(PPh3) (C), in combination with t-BuOK proved an effective and versatile catalyst allowing aromatic-, aliphatic- and cycloalkyl-containing alcohols to be efficiently converted to their corresponding ketones with high values of TON achievable.