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Royal Society of Chemistry, Catalysis Science & Technology, 6(7), p. 1297-1304, 2017

DOI: 10.1039/c6cy02413k

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Cooperative interplay between a flexible PNN-Ru(II) complex and a NaBH4 additive in the efficient catalytic hydrogenation of esters

Journal article published in 2017 by Zheng Wang ORCID, Xiangyang Chen ORCID, Bo Liu, Qing-Bin Liu, Gregory A. Solan ORCID, Xinzheng Yang, Wen-Hua Sun ORCID
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This paper is available in a repository.

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Abstract

Low catalyst loadings of the PNN-bearing ruthenium(ii) complex, [fac-PNN]RuH(PPh3)(CO), in combination with 5 mol% of NaBH4, efficiently catalyze the hydrogenation of a broad range of esters to their corresponding alcohols under mild pressures of H2.