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Royal Society of Chemistry, Dalton Transactions, 34(45), p. 13300-13303

DOI: 10.1039/c6dt02319c

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The doubly-bonded ditungsten anion [W2Cp2(μ-PPh2)(NO)2]−: an entry to the chemistry of unsaturated nitrosyl complexes

Journal article published in 2016 by M. Angeles Alvarez, M. Esther García, Daniel García-Vivó ORCID, Miguel A. Ruiz, Adrián Toyos
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The title complex, the first anionic nitrosyl complex featuring a metal-metal double bond, displays substantial nucleophilicity, thus providing synthetic access to different unsaturated hydride and heterometallic derivatives, as well as a variety of electron-precise molecules.