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Royal Society of Chemistry, Chemical Communications, 50(48), p. 6229

DOI: 10.1039/c2cc32018e

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Copper-induced N–N bond cleavage results in an octanuclear expanded-core grid-like complex

Journal article published in 2012 by Nicholas G. White, Jonathan A. Kitchen ORCID, John A. Joule, Sally Brooker ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Reaction of copper(I) acetate and 4-amino-3,5-di(2-pyridyl)-1,2,4-triazole (adpt) in methanol under ambient conditions yields octanuclear [CuII8(dpt)4(OH)4(OAc)8]; OAc = acetate anion, and dpt− = anion of deaminated adpt, 3,5-di(2-pyridyl)-1,2,4-triazolate. However, reaction of copper(II) acetate with dptH gives tetranuclear [CuII4(dpt)2(OH)(OMe)(OAc)4].