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Royal Society of Chemistry, Dalton Transactions

DOI: 10.1039/c5dt04724b

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Insertion and C–C coupling processes in reactions of the unsaturated hydride [W2Cp2(H)(μ-PCy2)(CO)2] with alkynes

Journal article published in 2016 by M. Angeles Alvarez, M. Esther García, Daniel García-Vivó ORCID, Miguel A. Ruiz, M. Fernanda Vega
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This paper is available in a repository.

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Abstract

Alkyne insertion into the W–H bond invariably occurs in the title reactions, to give alkenyl complexes which may undergo further alkyne addition to yield hydrocarbyl-bridged derivatives generated from alkenyl–alkyne coupling.