The reactivity of 1,1-dichloro-2,2-di-tert-butyldiphosphane towards lithiated metal carbonyls: a new entry to phosphanylphosphinidene dimers
Journal article published in 2016 by
Rafał Grubba 
,
Mateusz Zauliczny,
Łukasz Ponikiewski,
Jerzy Pikies
,
Mateusz Zauliczny,
Łukasz Ponikiewski,
Jerzy Pikies
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Abstract
Reactions of [Cp*(OC)3M]Li (Cp* = C5Me5, M = Mo, W) towards t-Bu2P–PCl2 lead to the formation of phosphanylphosphinidene dimers [Cp*(OC)3M(η2-t-Bu2P–P)]2 in fairly good yields.