Royal Society of Chemistry, Chemical Communications, 17(47), p. 4926
DOI: 10.1039/c1cc10862j
Full text: Unavailable
The first Group 4 alkoxyimido compounds are reported. The Ti=N-OtBu group in Ti(N2NMe)(NOtBu)(py) undergoes facile 2-electron N-O bond cleavage with PhCCMe as the reductant to form a 1,2-diamidoalkene group via two highly selective N-C bond forming events.