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Royal Society of Chemistry, Chemical Communications, 17(47), p. 4926

DOI: 10.1039/c1cc10862j

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Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands

Journal article published in 2011 by Andrew D. Schwarz, Ainara Nova-Flores ORCID, Eric Clot, Philip Mountford
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The first Group 4 alkoxyimido compounds are reported. The Ti=N-OtBu group in Ti(N2NMe)(NOtBu)(py) undergoes facile 2-electron N-O bond cleavage with PhCCMe as the reductant to form a 1,2-diamidoalkene group via two highly selective N-C bond forming events.