Published in
Royal Society of Chemistry, Chemical Communications, 11, p. 1334
DOI: 10.1039/b822236c
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Preparation and structure of the unique silicon(iv) cation [SiF3(Me3tacn)]+
Journal article published in 2009 by
Fei Cheng,
Andrew L. Hector 
,
William Levason,
Gillian Reid,
Michael Webster,
Wenjian Zhang
,
William Levason,
Gillian Reid,
Michael Webster,
Wenjian Zhang
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Abstract
The trifluorosilicon(IV) cation [SiF3(Me3tacn)]+, isolated as salts with [SiF5]-, [B{3,5-(CF3)2C6H3}4]- or Cl-, is obtained by reaction of SiF4 with Me3tacn under anhydrous conditions, and compared with the tetrafluoro complexes [SiF4(tmeda)] and [SiF4{2-Me2N(CH2)2NMe(CH2)2NMe2(CH2Cl)}][SiF5] obtained with the acyclic di- and tri-amines.