Published in

Royal Society of Chemistry, Journal of Analytical Atomic Spectrometry, 2(32), p. 415-419, 2017

DOI: 10.1039/c6ja00282j

Links

Tools

Export citation

Search in Google Scholar

Inter-calibration of a proposed new primary reference standard AA-ETH Zn for zinc isotopic analysis

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Green circle
Preprint: archiving allowed
Orange circle
Postprint: archiving restricted
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

We have prepared a large volume of pure, concentrated and homogenous zinc standard solution. This new standard solution is intended to be used as a primary reference standard for the zinc isotope community, and to serve as a replacement for the near-exhausted current reference standard, the so-called JMC-Lyon Zn. The isotopic composition of this new zinc standard (AA-ETH Zn) has been determined th rough an inter-laboratory calibration exercise, calibrated against the existing JMC-Lyon standard, as well as the certified Zn reference standard IRMM-3702. The data show that the new standard is isotopically indistinguishable from the IRMM-3702 zinc sta ndard, with a weighted ??? 66/64 Zn value of 0.28??0.02 ??? relative to JMC-Lyon. We suggest that this ne w standard be assigned a value ??? 66/64 Zn of +0.28 ??? for reporting of future Zn isotope data, with the ra tionale that all existi ng published Zn isotope data are presented relative to the JMC-Lyon standard. Theref ore our proposed presentation allows a direct comparison with all previously pu blished data, and that is directly traceable to a certified reference standard, IRMM-3702 Zn. This standard will be made freely available to all interested labs th rough contact with th e corresponding author.