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Royal Society of Chemistry, Chemical Communications, 79(52), p. 11760-11763

DOI: 10.1039/c6cc05777b

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KNH2-KH: A metal amide-hydride solid solution

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

SeriesInformation ; Chemical communications 52(79), 11760 - 11763(2016). doi:10.1039/C6CC05777B ; Abstract ; We report for the first time the formation of a metal amide–hydridesolid solution. The dissolution of KH into KNH$_2$ leads to an anionicsubstitution, which decreases the interaction among NH$_2$-ions.The rotational properties of the high temperature polymorphs of KNH$_2$ are thereby retained down to room temperature. ; Other ; Published by Soc., Cambridge