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Royal Society of Chemistry, Chemical Communications, 79(52), p. 11760-11763

DOI: 10.1039/c6cc05777b

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KNH2-KH: A metal amide-hydride solid solution

Journal article published in 2016 by Antonio Santoru ORCID, Claudio Pistidda, Magnus H. Sørby, Michele R. Chierotti ORCID, Sebastiano Garroni, Eugenio Pinatel, Fahim Karimi, Hujun Cao, Nils Bergemann, Thi T. Le, Julián Puszkiel, Roberto Gobetto, Marcello Baricco ORCID, Bjørn C. Hauback, Thomas Klassen and other authors.
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

SeriesInformation ; Chemical communications 52(79), 11760 - 11763(2016). doi:10.1039/C6CC05777B ; Abstract ; We report for the first time the formation of a metal amide–hydridesolid solution. The dissolution of KH into KNH$_2$ leads to an anionicsubstitution, which decreases the interaction among NH$_2$-ions.The rotational properties of the high temperature polymorphs of KNH$_2$ are thereby retained down to room temperature. ; Other ; Published by Soc., Cambridge