Published in
Royal Society of Chemistry, Chemical Communications, 63(52), p. 9833-9836
DOI: 10.1039/c6cc03431d
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Contrasted photochromic and luminescent properties in dinuclear Pt(II) complexes linked through a central dithienylethene unit
Journal article published in 2016 by
Julien Boixel,
Yifan Zhu,
Hubert Le Bozec,
Mohamed Ali Benmensour,
Abdou Boucekkine,
Keith Man-Chung Wong,
Alessia Colombo,
Dominique Roberto,
Véronique Guerchais 
,
Denis Jacquemin
,
Denis Jacquemin
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Abstract
We disclose two unprecedented complexes built with a central dithienylethene photochrome connecting two cyclometalated Pt(ii) moieties either on the reactive carbon atoms or on the lateral non-reactive carbon atoms of the photochrome. The two systems show vastly different properties that are rationalised thanks to quantum-chemical calculations.