Published in
Royal Society of Chemistry, Polymer Chemistry, 38(7), p. 5930-5942, 2016
DOI: 10.1039/c6py01307d
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Ultrafast SET-LRP in biphasic mixtures of the non-disproportionating solvent acetonitrile with water
Journal article published in 2016 by
Mojtaba Enayati,
Ryan L. Jezorek,
Rauan B. Smail,
Michael J. Monteiro 
,
Virgil Percec
,
Virgil Percec
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Abstract
The two kinetic regime, low conversion and low chain end functionality seen in copper catalyzed polymerization of acrylates in acetonitrile was transformed into a SET-LRP kinetic, to complete conversion and quantitative chain end functionality in a biphasic mixture containing 10% water.