Published in
Royal Society of Chemistry, Chemical Communications, 79(52), p. 11783-11786
DOI: 10.1039/c6cc06059e
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Supramolecular assembly of cobaloxime on nanoring-coated carbon nanotubes: addressing the stability of the pyridine-cobalt linkage under hydrogen evolution turnover conditions.
Journal article published in 2016 by
Simon Donck,
Jennifer Fize,
Edmond Gravel 
,
Eric Doris,
Vincent Artero
,
Eric Doris,
Vincent Artero
This paper was not found in any repository, but could be made available legally by the author.
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Abstract
A carbon nanotube-cobaloxime nanohybrid was prepared through supramolecular assembly of tailored polymerizable amphiphiles, leading to the coordination of cobalt on pyridine-coated nanotubes. This material was used as a catalyst for hydrogen evolution in fully aqueous media. This study provides a definitive asset regarding the stability of the pyridine-cobalt axial bond under H2 evolution turnover conditions.