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Royal Society of Chemistry, Dalton Transactions, 32(45), p. 12644-12648

DOI: 10.1039/c6dt02415g

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New N^C^N-coordinated Pd(II) and Pt(II) complexes of a tridentate N-heterocyclic carbene ligand featuring a 6-membered central ring: synthesis, structures and luminescence

Journal article published in 2016 by Jamal Moussa, Kamel Haddouche, Lise-Marie Chamoreau, Hani Amouri, J. A. Gareth Williams ORCID
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This paper is available in a repository.

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Abstract

We describe Pd(II) and Pt(II) complexes of an N^C^N-coordinating pincer-like ligand featuring two lateral pyridine rings and a 6-membered carbene core. Their crystal structures display 1-dimensional chains with short π–π and M(II)⋯M(II) interactions. Such interactions also impact on the photophysical properties, with the Pt(II) complex being luminescent in the solid state at room temperature.