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Royal Society of Chemistry, Chemical Communications, 98(48), p. 11981

DOI: 10.1039/c2cc37221e

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Reversible Binding of Nitric Oxide to an Fe(III) Complex of a Tetra-amido Macrocycle

Journal article published in 2012 by Michael D. Pluth ORCID, Stephen J. Lippard
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Nitric oxide binds reversibly to the Fe(iii) complex of a well-developed tetra-amido macrocyclic ligand. Reaction with NO results in formation of a species consistent with an S = 1 {Fe-NO}(6) ground state as characterized by UV-vis, IR, EPR, and Mössbauer spectroscopy. The resultant nitrosyl is labile and dissociates readily upon purging with N(2), thus providing a rare example of reversible NO binding to non-heme iron.