Complexes of H 3 N⋯CuF and H 3 N⋯CuI have been synthesised in the gas phase and characterized by microwave spectroscopy. The rotational spectra of 4 isotopologues of H 3 N⋯CuF and 5 isotopologues of H 3 N⋯CuI have been measured in the 6.5-18.5 GHz frequency range using a chirped-pulse Fourier transform microwave spectrometer. Each complex is generated from a gas sample containing NH 3 and a halogen-containing precursor diluted in Ar. Copper is introduced by laser ablation of a solid target prior to supersonic expansion of the sample into the vacuum chamber of the microwave spectrometer. The spectrum of each complex is characteristic of a symmetric rotor and a C 3v geometry in which the N, Cu and X atoms (where X is F or I) lie on the Ca3 axis. The rotational constant (B 0 ), centrifugal distortion constants (D J and D JK ), nuclear spin-rotation (C bb (Cu) = C cc (Cu)) constant (for H 3 N⋯CuF only) and nuclear quadrupole coupling constants (χ aa (X) where (X = N, Cu, I)) are fitted to the observed transition frequencies. Structural parameters are determined from the measured rotational constants and also calculated ab initio at the CCSD(T)(F12∗)/AVQZ level of theory. Force constants describing the interaction between ammonia and each metal halide are determined from D J for each complex. Trends in the interaction strengths and geometries of B⋯CuX (B = NH 3 , CO) (X = F, Cl, Br, I) are discussed.