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Royal Society of Chemistry, Chemical Communications, 35(52), p. 5997-6000, 2016

DOI: 10.1039/c6cc02284g

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Radical Perfluoroalkylation – Easy Access to 2 Perfluoroalkylindol-3-imines via Electron Catalysis

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Arylisonitriles react with alkyl and perfluoroalkyl radicals to form 2-alkylated indole-3-iminesviatwo sequential additions to the isonitrile moiety followed by homolytic aromatic substitution.