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Royal Society of Chemistry, Dalton Transactions

DOI: 10.1039/c6dt00422a

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Voltage clustering in redox-active ligand complexes: mitigating electronic communication through choice of metal ion

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Homoleptic bis(imino)acenaphthene complexes of aluminum, chromium, and gallium were synthesized, characterized and modeled to compare the orbital contributions of main group elements and transition metals in ligand-based redox events toward increasing energy density of battery electrolytes.