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Royal Society of Chemistry, Chemical Communications, 35(52), p. 5916-5919, 2016

DOI: 10.1039/c6cc00782a

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Highly Selective Markovnikov Hydroboration of Alkyl-Substituted Terminal Alkenes with a Phosphine-Copper(I) Catalyst

Journal article published in 2016 by Hiroaki Iwamoto, Koji Kubota ORCID, Hajime Ito
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A new method has been developed for the Markovnikov hydroboration of alkyl-substituted terminal alkenes. The use of bulky bisphosphine–copper(i) catalyst system resulted in high regioselectivity to afford the corresponding secondary alkylboronates (branch/linear = 92 : 8–97 : 3).