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Royal Society of Chemistry, Dalton Transactions, 5(45), p. 2172-2179

DOI: 10.1039/c5dt03085d

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An investigation on the chemistry of the R2PP ligand: reactions of a phosphanylphosphinidene complex of tungsten(vi) with electrophilic reagents

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The nucleophilic properties of the title compound [(2,6-i-Pr2C6H3N)2(Cl)W(η2-t-Bu2PP)]Li·3DME (1) were investigated in reactions with selected electrophilic reagents such as MeI, M(CO)5THF (M = Cr, Mo, W), AlCl3, and GaCl3.