Published in
Royal Society of Chemistry, Chemical Communications, 3(51), p. 576-579, 2015
DOI: 10.1039/c4cc08152h
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Bimetallic zinc complex – active species in coupling of terminal alkynes with aldehydes via nucleophilic addition/Oppenauer oxidation
Journal article published in 2015 by
Jiwen Yuan,
Jing Wang,
Guanghui Zhang 
,
Chao Liu ,
Xiaotian Qi,
Yu Lan,
Jeffrey T. Miller,
A. Jeremy Kropf,
Emilio E. Bunel,
Aiwen Lei
,
Chao Liu ,
Xiaotian Qi,
Yu Lan,
Jeffrey T. Miller,
A. Jeremy Kropf,
Emilio E. Bunel,
Aiwen Lei
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Abstract
A mechanistic study on the zinc-promoted coupling between aldehydes and terminal alkynes was demonstrated. A bimetallic zinc complex was determined to be the active species.