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Royal Society of Chemistry, Chemical Communications, 91(51), p. 16342-16345

DOI: 10.1039/c5cc06984j

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Selective catalytic deuteration of phosphorus ligands using ruthenium nanoparticles: a new approach to gain information on ligand coordination

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Selective deuteration of phenyl rings in phenyl-alkyl phosphines, including diphosphines, was achieved using Ru/PVP nanoparticles and D2, which enables the comprehension of how different phosphorus ligands coordinate to the nanoparticle surface.